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Generation and direct observation of a triplet arylnitrenium ion

Nitrenium ions are important reactive intermediates in both chemistry and biology. Although singlet nitrenium ions are well-characterized by direct methods, the triplet states of nitrenium ions have never been directly detected. Here, we find that the excited state of the photoprecursor partitions b...

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Detalles Bibliográficos
Autores principales: Du, Lili, Wang, Juanjuan, Qiu, Yunfan, Liang, Runhui, Lu, Penglin, Chen, Xuebo, Phillips, David Lee, Winter, Arthur H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9203820/
https://www.ncbi.nlm.nih.gov/pubmed/35710806
http://dx.doi.org/10.1038/s41467-022-31091-z