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A large negative magnetoresistance effect in semiconducting crystals composed of an octahedrally ligated phthalocyanine complex with high-spin manganese(iii)
A design for an octahedrally ligated phthalocyanine complex with high-spin manganese(iii) (S = 2) and Mn(III)(Pc)Cl(2) (Pc = phthalocyanine) is presented. The presence of high-spin state Mn(III) in the fabricated Ph(4)P[Mn(III)(Pc)Cl(2)](2) (Ph(4)P = tetraphenylphosphonium) semiconducting molecular...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204555/ https://www.ncbi.nlm.nih.gov/pubmed/35765347 http://dx.doi.org/10.1039/d2ra00188h |