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A large negative magnetoresistance effect in semiconducting crystals composed of an octahedrally ligated phthalocyanine complex with high-spin manganese(iii)

A design for an octahedrally ligated phthalocyanine complex with high-spin manganese(iii) (S = 2) and Mn(III)(Pc)Cl(2) (Pc = phthalocyanine) is presented. The presence of high-spin state Mn(III) in the fabricated Ph(4)P[Mn(III)(Pc)Cl(2)](2) (Ph(4)P = tetraphenylphosphonium) semiconducting molecular...

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Detalles Bibliográficos
Autores principales: Mine, Kosuke, Yamaguchi, Masayuki, Murakawa, Hiroshi, Hanasaki, Noriaki, Matsuda, Masaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204555/
https://www.ncbi.nlm.nih.gov/pubmed/35765347
http://dx.doi.org/10.1039/d2ra00188h

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