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Control of Fe(3+) coordination by excess Cl(−) in alcohol solutions

We spectroscopically investigated coordination state of Fe(3+) in methanol (MeOH) and ethanol (EtOH) solutions against Cl(−) concentration ([Cl(−)]). In both the system, we observed characteristic absorption bands due to the FeCl(4) complex at high-[Cl(−)] region. In the MeOH system, the proportion...

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Detalles Bibliográficos
Autores principales: Nomura, Yunika, Inoue, Dai, Moritomo, Yutaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204708/
https://www.ncbi.nlm.nih.gov/pubmed/35765349
http://dx.doi.org/10.1039/d2ra01522f