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Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage

Transition metal-catalyzed C–C bond cleavage is a powerful tool for the reconstruction of a molecular skeleton. We report herein the multi-carbon homologation of aryl ketones to long-chain ketones and aldehydes via ligand-promoted Ar−C(O) bond cleavage and subsequent cross coupling with alkenols. Va...

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Detalles Bibliográficos
Autores principales: Wang, Xing, Li, Ling-Jun, Wang, Zhen-Yu, Xu, Hui, Dai, Hui-Xiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204744/
https://www.ncbi.nlm.nih.gov/pubmed/35720269
http://dx.doi.org/10.1016/j.isci.2022.104505