Photoinduced Autonomous Nonequilibrium Operation of a Molecular Shuttle by Combined Isomerization and Proton Transfer Through a Catalytic Pathway

[Image: see text] We describe a [2]rotaxane whose recognition sites for the ring are a dibenzylammonium moiety, endowed with acidic and H-bonding donor properties, and an imidazolium center bearing a photoactive phenylazo substituent. Light irradiation of this compound triggers a network of E/Z isom...

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Detalles Bibliográficos
Autores principales: Nicoli, Federico, Curcio, Massimiliano, Tranfić Bakić, Marina, Paltrinieri, Erica, Silvi, Serena, Baroncini, Massimo, Credi, Alberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204767/
https://www.ncbi.nlm.nih.gov/pubmed/35575701
http://dx.doi.org/10.1021/jacs.1c13537

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204767/
https://www.ncbi.nlm.nih.gov/pubmed/35575701
http://dx.doi.org/10.1021/jacs.1c13537

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