Asymmetric Cationic Polymerization of Benzofuran through a Reversible Chain-Transfer Mechanism: Optically Active Polybenzofuran with Controlled Molecular Weights

[Image: see text] Benzofuran (BzF) is a prochiral, 1,2-disubstituted, unsymmetric cyclic olefin that can afford optically active polymers by asymmetric polymerization, unlike common acyclic vinyl monomers. Although asymmetric cationic polymerization of BzF was reported by Natta et al. in the 1960s,...

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Detalles Bibliográficos
Autores principales: Uchiyama, Mineto, Watanabe, Daichi, Tanaka, Yuhei, Satoh, Kotaro, Kamigaito, Masami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204774/
https://www.ncbi.nlm.nih.gov/pubmed/35658439
http://dx.doi.org/10.1021/jacs.2c02569

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204774/
https://www.ncbi.nlm.nih.gov/pubmed/35658439
http://dx.doi.org/10.1021/jacs.2c02569

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