Cargando…

Catalyst-free reductive cyclization of bis(2-aminophenyl) disulfide with CO(2) in the presence of BH(3)NH(3) to synthesize 2-unsubstituted benzothiazole derivatives

An efficient and catalyst-free methodology for the reductive cyclization of various disulfides using BH(3)NH(3) as a reductant and CO(2) as a C1 resource was developed. The desired 2-unsubstituted benzothiazole derivatives were obtained in good to excellent yields. Moreover, mechanism investigation...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Xiao, Liu, Zhenbao, Hong, Hailong, Han, Limin, Zhu, Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9208316/
https://www.ncbi.nlm.nih.gov/pubmed/35800324
http://dx.doi.org/10.1039/d2ra03134e