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Atomic-scale changes of silica-supported catalysts with nanocrystalline or amorphous gallia phases: implications of hydrogen pretreatment on their selectivity for propane dehydrogenation

This work explores how H(2) pretreatment at 550 °C induces structural transformation of two gallia-based propane dehydrogenation (PDH) catalysts, viz. nanocrystalline γ/β-Ga(2)O(3) and amorphous Ga(2)O(3) (GaO(x)) supported on silica (γ-Ga(2)O(3)/SiO(2) and Ga/SiO(2), respectively) and how it affect...

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Detalles Bibliográficos
Autores principales: Castro-Fernández, Pedro, Serykh, Alexander I., Yakimov, Alexander V., Prosvirin, Igor P., Bukhtiyarov, Andrey V., Abdala, Paula M., Copéret, Christophe, Fedorov, Alexey, Müller, Christoph R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9208381/
https://www.ncbi.nlm.nih.gov/pubmed/35814525
http://dx.doi.org/10.1039/d2cy00074a