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Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes

Chiral organoborons are of great value in asymmetric synthesis, functional materials, and medicinal chemistry. The development of chiral bis(boryl) alkanes, especially optically enriched 1,1-diboron compounds, has been greatly inhibited by the lack of direct synthetic protocols. Therefore, it is ver...

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Detalles Bibliográficos
Autores principales: Jin, Shengnan, Li, Jinxia, Liu, Kang, Ding, Wei-Yi, Wang, Shuai, Huang, Xiujuan, Li, Xue, Yu, Peiyuan, Song, Qiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9209482/
https://www.ncbi.nlm.nih.gov/pubmed/35725731
http://dx.doi.org/10.1038/s41467-022-31234-2