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Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
Chiral organoborons are of great value in asymmetric synthesis, functional materials, and medicinal chemistry. The development of chiral bis(boryl) alkanes, especially optically enriched 1,1-diboron compounds, has been greatly inhibited by the lack of direct synthetic protocols. Therefore, it is ver...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9209482/ https://www.ncbi.nlm.nih.gov/pubmed/35725731 http://dx.doi.org/10.1038/s41467-022-31234-2 |