Cargando…

Selective Functionalization of Arene C(sp(2))–H Bonds by Gold Catalysis: The Role of Carbene Substituents

[Image: see text] The complete regioselective incorporation of carbene units to nonactivated arene rings has been achieved employing gold(I) catalysts bearing alkoxydiaminophosphine ligands, with readily available, nonelaborated ethyl 2-phenyldiazoacetate as the carbene source. These results are in...

Descripción completa

Detalles Bibliográficos
Autores principales: Pizarro, Juan Diego, Schmidtke, Inga L., Nova, Ainara, Fructos, Manuel R., Pérez, Pedro J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9210454/
https://www.ncbi.nlm.nih.gov/pubmed/35756859
http://dx.doi.org/10.1021/acscatal.2c01713