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Kinetics and Reaction Mechanism of Biothiols Involved in S(N)Ar Reactions: An Experimental Study
Few kinetic parameters, or reaction rates, are known up to date in detail about 1-chloro and 1-fluoro-2,4-dinitrobenzene (ClDNB and FDNB, respectively) with a series of biothiols in aqueous media. These biological nucleophiles with thiol groups have been widely used as a reference in nucleophile rea...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Frontiers Media S.A.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9213796/ https://www.ncbi.nlm.nih.gov/pubmed/35755252 http://dx.doi.org/10.3389/fchem.2022.854918 |