Single molecule demonstration of Debye–Stokes–Einstein breakdown in polystyrene near the glass transition temperature

Rotational-translational decoupling, in which translational motion is apparently enhanced over rotational motion in violation of Stokes-Einstein (SE) and Debye-Stokes-Einstein (DSE) predictions, has been observed in materials near their glass transition temperatures (T(g)). This has been posited to...

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Detalles Bibliográficos
Autores principales: Mandel, Nicole L., Lee, Soohyun, Kim, Kimyung, Paeng, Keewook, Kaufman, Laura J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9226357/
https://www.ncbi.nlm.nih.gov/pubmed/35739122
http://dx.doi.org/10.1038/s41467-022-31318-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9226357/
https://www.ncbi.nlm.nih.gov/pubmed/35739122
http://dx.doi.org/10.1038/s41467-022-31318-z

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