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Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes

The coordination chemistry of the N-heterocyclic carbene ligand IMes((NMe2)2), derived from the well-known IMes ligand by substitution of the carbenic heterocycle with two dimethylamino groups, was investigated with d(6) [Mn(I), Fe(II)], d(8) [Rh(I)], and d(10) [Cu(I)] transition-metal centers. The...

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Detalles Bibliográficos
Autores principales: Ruamps, Mirko, Bastin, Stéphanie, Rechignat, Lionel, Sournia-Saquet, Alix, Vendier, Laure, Lugan, Noël, Mouesca, Jean-Marie, Valyaev, Dmitry A., Maurel, Vincent, César, Vincent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227367/
https://www.ncbi.nlm.nih.gov/pubmed/35744903
http://dx.doi.org/10.3390/molecules27123776