Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp(3)C–P bonds

Direct phosphorylation of benzylic C–H bonds was achieved in a biphasic system under transition metal-free conditions. A selective radical/radical sp(3)C–H/P(O)–H cross coupling was proposed, and various substituted toluenes were applicable. The transformation provided a promising method for constru...

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Detalles Bibliográficos
Autores principales: Li, Qiang, Zhao, Chang-Qiu, Chen, Tieqiao, Han, Li-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227801/
https://www.ncbi.nlm.nih.gov/pubmed/35799919
http://dx.doi.org/10.1039/d2ra02812c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227801/
https://www.ncbi.nlm.nih.gov/pubmed/35799919
http://dx.doi.org/10.1039/d2ra02812c

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