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Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp(3)C–P bonds
Direct phosphorylation of benzylic C–H bonds was achieved in a biphasic system under transition metal-free conditions. A selective radical/radical sp(3)C–H/P(O)–H cross coupling was proposed, and various substituted toluenes were applicable. The transformation provided a promising method for constru...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227801/ https://www.ncbi.nlm.nih.gov/pubmed/35799919 http://dx.doi.org/10.1039/d2ra02812c |