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Tuning Selectivity in the Direct Conversion of Methane to Methanol: Bimetallic Synergistic Effects on the Cleavage of C–H and O–H Bonds over NiCu/CeO(2) Catalysts

[Image: see text] The efficient activation of methane and the simultaneous water dissociation are crucial in many catalytic reactions on oxide-supported transition metal catalysts. On very low-loaded Ni/CeO(2) surfaces, methane easily fully decomposes, CH(4) → C + 4H, and water dissociates, H(2)O→ O...

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Detalles Bibliográficos
Autores principales: Lustemberg, Pablo G., Senanayake, Sanjaya D., Rodriguez, José A., Ganduglia-Pirovano, M. Verónica
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9234976/
https://www.ncbi.nlm.nih.gov/pubmed/35699247
http://dx.doi.org/10.1021/acs.jpclett.2c00885