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[Cu(18)H(3)(S-Adm)(12)(PPh(3))(4)Cl(2)]: fusion of Platonic and Johnson solids through a Cu(0) center and its photophysical properties
Structural elucidation of atom-precise thiolate-protected copper nanoclusters (Cu NCs) containing Cu(0) is quite challenging. Here, we report a new adamantane-thiol-protected NC, [Cu(18)H(3)(S-Adm)(12)(PPh(3))(4)Cl(2)] (Cu(18)), which represents the first observation of a rare mononuclear Cu(0)-cont...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241973/ https://www.ncbi.nlm.nih.gov/pubmed/35872832 http://dx.doi.org/10.1039/d2sc02544b |