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Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different

In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of hydrosilanes and hydroboranes (tri- and tetra-coordinated) in an electrophilic manner, avoiding the need for the metal centre to undergo two-electron processes (oxidative additio...

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Detalles Bibliográficos
Autores principales: Ríos, Pablo, Rodríguez, Amor, Conejero, Salvador
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241980/
https://www.ncbi.nlm.nih.gov/pubmed/35872827
http://dx.doi.org/10.1039/d2sc02324e