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Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H(2) and D(2)
Ligand exchange reactions of [Rh(COD){η(4)-Ge(9)(Hyp)(3)}] with L-type nucleophiles such as PMe(3), PPh(3), IMe(4) (IMe(4) = 1,3,4,5-tetramethylimidazol-2-ylidene) or [W(Cp)(2)H(2)] result in the displacement of the COD ligand to afford clusters with coordinatively unsaturated trigonal pyramidal rho...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9242017/ https://www.ncbi.nlm.nih.gov/pubmed/35872810 http://dx.doi.org/10.1039/d2sc02552c |