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Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H(2) and D(2)

Ligand exchange reactions of [Rh(COD){η(4)-Ge(9)(Hyp)(3)}] with L-type nucleophiles such as PMe(3), PPh(3), IMe(4) (IMe(4) = 1,3,4,5-tetramethylimidazol-2-ylidene) or [W(Cp)(2)H(2)] result in the displacement of the COD ligand to afford clusters with coordinatively unsaturated trigonal pyramidal rho...

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Detalles Bibliográficos
Autores principales:	Townrow, Oliver P. E., Duckett, Simon B., Weller, Andrew S., Goicoechea, Jose M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9242017/ https://www.ncbi.nlm.nih.gov/pubmed/35872810 http://dx.doi.org/10.1039/d2sc02552c

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