Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage

The classical route to the PMe(3)-stabilised polycyclic aromatic hydrocarbon (PAH)-substituted diborenes B(2)Ar(2)(PMe(3))(2) (Ar = 9-phenanthryl 7-Phen; Ar = 1-pyrenyl 7-Pyr) via the corresponding 1,2-diaryl-1,2-dimethoxydiborane(4) precursors, B(2)Ar(2)(OMe)(2), is marred by the systematic decompo...

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Detalles Bibliográficos
Autores principales: Okorn, Alexander, Jayaraman, Arumugam, Englert, Lukas, Arrowsmith, Merle, Swoboda, Theresa, Weigelt, Jeanette, Brunecker, Carina, Hess, Merlin, Lamprecht, Anna, Lenczyk, Carsten, Rang, Maximilian, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9242019/
https://www.ncbi.nlm.nih.gov/pubmed/35872817
http://dx.doi.org/10.1039/d2sc02515a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9242019/
https://www.ncbi.nlm.nih.gov/pubmed/35872817
http://dx.doi.org/10.1039/d2sc02515a

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