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Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage
The classical route to the PMe(3)-stabilised polycyclic aromatic hydrocarbon (PAH)-substituted diborenes B(2)Ar(2)(PMe(3))(2) (Ar = 9-phenanthryl 7-Phen; Ar = 1-pyrenyl 7-Pyr) via the corresponding 1,2-diaryl-1,2-dimethoxydiborane(4) precursors, B(2)Ar(2)(OMe)(2), is marred by the systematic decompo...
| Autores principales: | , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9242019/ https://www.ncbi.nlm.nih.gov/pubmed/35872817 http://dx.doi.org/10.1039/d2sc02515a |