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Facile and general electrochemical deuteration of unactivated alkyl halides

Herein, a facile and general electroreductive deuteration of unactivated alkyl halides (X = Cl, Br, I) or pseudo-halides (X = OMs) using D(2)O as the economical deuterium source was reported. In addition to primary and secondary alkyl halides, sterically hindered tertiary chlorides also work very we...

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Detalles Bibliográficos
Autores principales: Li, Pengfei, Guo, Chengcheng, Wang, Siyi, Ma, Dengke, Feng, Tian, Wang, Yanwei, Qiu, Youai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9247074/
https://www.ncbi.nlm.nih.gov/pubmed/35773255
http://dx.doi.org/10.1038/s41467-022-31435-9