Dissociation of Pyridinethiolate Ligands during Hydrogen Evolution Reactions of Ni-Based Catalysts: Evidence from X-ray Absorption Spectroscopy

[Image: see text] The protonation of several Ni-centered pyridine-2-thiolate photocatalysts for hydrogen evolution is investigated using X-ray absorption spectroscopy (XAS). While protonation of the pyridinethiolate ligand was previously thought to result in partial dechelation from the metal at the...

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Detalles Bibliográficos
Autores principales: Ledbetter, Kathryn, Larsen, Christopher B., Lim, Hyeongtaek, Zoric, Marija R., Koroidov, Sergey, Pemmaraju, C. Das, Gaffney, Kelly J., Cordones, Amy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9257748/
https://www.ncbi.nlm.nih.gov/pubmed/35732599
http://dx.doi.org/10.1021/acs.inorgchem.2c00167

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9257748/
https://www.ncbi.nlm.nih.gov/pubmed/35732599
http://dx.doi.org/10.1021/acs.inorgchem.2c00167

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