Strong non-Arrhenius behavior at low temperatures in the OH + HCl → H(2)O + Cl reaction due to resonance induced quantum tunneling

The OH + HCl → H(2)O + Cl reaction releases Cl atoms, which can catalyze the ozone destruction reaction in the stratosphere. The measured rate coefficients for the reaction deviate substantially from the Arrhenius limit at low temperatures and become essentially independent of temperature when T <...

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Detalles Bibliográficos
Autores principales: Xu, Xin, Chen, Jun, Lu, Xiaoxiao, Fang, Wei, Liu, Shu, Zhang, Dong H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9258319/
https://www.ncbi.nlm.nih.gov/pubmed/35865883
http://dx.doi.org/10.1039/d2sc01958b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9258319/
https://www.ncbi.nlm.nih.gov/pubmed/35865883
http://dx.doi.org/10.1039/d2sc01958b

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