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Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H bonds as well as the aziridination of olefines. We report on the synthesis of the trigonal imido iron complexes [Fe(NMes)L(2)](0,−) (L = –N{Dipp}SiMe(3)); Dipp = 2,6-diisopropyl-phenyl; Mes = (2,4,6-...

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Detalles Bibliográficos
Autores principales: Reith, Sascha, Demeshko, Serhiy, Battistella, Beatrice, Reckziegel, Alexander, Schneider, Christian, Stoy, Andreas, Lichtenberg, Crispin, Meyer, Franc, Munz, Dominik, Werncke, C. Gunnar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9258327/
https://www.ncbi.nlm.nih.gov/pubmed/35865905
http://dx.doi.org/10.1039/d2sc01088g