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Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9259713/ https://www.ncbi.nlm.nih.gov/pubmed/35132810 http://dx.doi.org/10.1002/advs.202105785 |