Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology

Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topo...

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Detalles Bibliográficos
Autores principales: Leitner, Tanja Desirée, von Glasenapp, Jan Simon, Herges, Rainer, Mena‐Osteritz, Elena, Bäuerle, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9259713/
https://www.ncbi.nlm.nih.gov/pubmed/35132810
http://dx.doi.org/10.1002/advs.202105785
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author Leitner, Tanja Desirée
von Glasenapp, Jan Simon
Herges, Rainer
Mena‐Osteritz, Elena
Bäuerle, Peter
author_facet Leitner, Tanja Desirée
von Glasenapp, Jan Simon
Herges, Rainer
Mena‐Osteritz, Elena
Bäuerle, Peter
author_sort Leitner, Tanja Desirée
collection PubMed
description Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.
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spelling pubmed-92597132022-07-11 Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology Leitner, Tanja Desirée von Glasenapp, Jan Simon Herges, Rainer Mena‐Osteritz, Elena Bäuerle, Peter Adv Sci (Weinh) Research Articles Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology. John Wiley and Sons Inc. 2022-02-08 /pmc/articles/PMC9259713/ /pubmed/35132810 http://dx.doi.org/10.1002/advs.202105785 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Leitner, Tanja Desirée
von Glasenapp, Jan Simon
Herges, Rainer
Mena‐Osteritz, Elena
Bäuerle, Peter
Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title_full Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title_fullStr Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title_full_unstemmed Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title_short Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
title_sort highly crowded twisted thienylene‐phenylene structures: evidence for through‐space orbital coupling in a [4]catenated topology
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9259713/
https://www.ncbi.nlm.nih.gov/pubmed/35132810
http://dx.doi.org/10.1002/advs.202105785
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