Facile Electrodeposition of NiCo(2)O(4) Nanosheets on Porous Carbonized Wood for Wood-Derived Asymmetric Supercapacitors
Multichannel-porous carbon derived from wood can serve as a conductive substrate for fast charge transfer and ion diffusion, supporting the high-theory capacitance of pseudocapacitive materials. Herein, NiCo(2)O(4) nanosheets, which are hierarchically porous, anchored on the surface of carbonized wo...
Autores principales: | , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9269009/ https://www.ncbi.nlm.nih.gov/pubmed/35808566 http://dx.doi.org/10.3390/polym14132521 |
Sumario: | Multichannel-porous carbon derived from wood can serve as a conductive substrate for fast charge transfer and ion diffusion, supporting the high-theory capacitance of pseudocapacitive materials. Herein, NiCo(2)O(4) nanosheets, which are hierarchically porous, anchored on the surface of carbonized wood via electrodeposition for free-binder high-performance supercapacitor electrode materials, were proposed. Benefiting from the effectively alleviated NiCo(2)O(4) nanosheets accumulation and sufficient active surface area for redox reaction, a N-doped wood-derived porous carbon-NiCo(2)O(4) nanosheet hybrid material (NCNS–NCW) electrode exhibited a specific electric capacity of 1730 F g(−1) at 1 A g(−1) in 1 mol L(−1) KOH and splendid electrochemical firmness with 80% capacitance retention after cycles. Furthermore, an all-wood-based asymmetric supercapacitor based on NCNS–NCW//NCW was assembled and a high energy density of 56.1 Wh kg(−1) at a watt density of 349 W kg(−1) was achieved. Due to the great electrochemical performance of NCNS–NCW, we expect it to be used as an electrode material with great promise for energy storage equipment. |
---|