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The stereochemical course of 2-methylisoborneol biosynthesis

Both enantiomers of 2-methyllinalyl diphosphate (2-Me-LPP) were synthesized enantioselectively using Sharpless epoxidation as a key step and purification of enantiomerically enriched intermediates through HPLC separation on a chiral stationary phase. Their enzymatic conversion with 2-methylisoborneo...

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Detalles Bibliográficos
Autores principales: Gu, Binbin, Hou, Anwei, Dickschat, Jeroen S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9273983/
https://www.ncbi.nlm.nih.gov/pubmed/35875708
http://dx.doi.org/10.3762/bjoc.18.82