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Enhancing the quantum yield of singlet oxygen: photocatalytic degradation of mustard gas simulant 2-chloroethyl ethyl sulfide catalyzed by a hybrid of polyhydroxyl aluminum cations and porphyrin anions
By combining the anionic salt meso-tetra(4-carboxyphenyl)porphyrin (TCPP(4−)) and the Keggin polyoxometalate cation cluster [Al(13)O(4)(OH)(24)(H(2)O)(12)](7+)via a simple ion-exchange method, a hybrid (C(48)H(26)N(4)O(8))[Al(13)O(4)(OH)(24)(H(2)O)(12)](2)(OH)(10)·18H(2)O (Al(13)–TCPP) was prepared...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9277536/ https://www.ncbi.nlm.nih.gov/pubmed/35919596 http://dx.doi.org/10.1039/d2ra01821g |