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Enhancing the quantum yield of singlet oxygen: photocatalytic degradation of mustard gas simulant 2-chloroethyl ethyl sulfide catalyzed by a hybrid of polyhydroxyl aluminum cations and porphyrin anions

By combining the anionic salt meso-tetra(4-carboxyphenyl)porphyrin (TCPP(4−)) and the Keggin polyoxometalate cation cluster [Al(13)O(4)(OH)(24)(H(2)O)(12)](7+)via a simple ion-exchange method, a hybrid (C(48)H(26)N(4)O(8))[Al(13)O(4)(OH)(24)(H(2)O)(12)](2)(OH)(10)·18H(2)O (Al(13)–TCPP) was prepared...

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Detalles Bibliográficos
Autores principales: Yang, Ying, Yin, Jianbo, Tao, Fangsheng, Zhou, Yunshan, Zhang, Lijuan, Zhong, Yuxu, Wang, Yong'an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9277536/
https://www.ncbi.nlm.nih.gov/pubmed/35919596
http://dx.doi.org/10.1039/d2ra01821g