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Nitrogen activation and cleavage by a multimetallic uranium complex

Multimetallic-multielectron cooperativity plays a key role in the metal-mediated cleavage of N(2) to nitrides (N(3−)). In particular, low-valent uranium complexes coupled with strong alkali metal reducing agents can lead to N(2) cleavage, but often, it is ambiguous how many electrons are transferred...

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Detalles Bibliográficos
Autores principales: Keener, Megan, Fadaei-Tirani, Farzaneh, Scopelliti, Rosario, Zivkovic, Ivica, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278153/
https://www.ncbi.nlm.nih.gov/pubmed/35919442
http://dx.doi.org/10.1039/d2sc02997a