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Nitrogen activation and cleavage by a multimetallic uranium complex
Multimetallic-multielectron cooperativity plays a key role in the metal-mediated cleavage of N(2) to nitrides (N(3−)). In particular, low-valent uranium complexes coupled with strong alkali metal reducing agents can lead to N(2) cleavage, but often, it is ambiguous how many electrons are transferred...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278153/ https://www.ncbi.nlm.nih.gov/pubmed/35919442 http://dx.doi.org/10.1039/d2sc02997a |