Switchable photocatalysis for the chemodivergent benzylation of 4-cyanopyridines

We report a photocatalytic strategy for the chemodivergent radical benzylation of 4-cyanopyridines. The chemistry uses a single photoredox catalyst to generate benzyl radicals upon N–F bond activation of 2-alkyl N-fluorobenzamides. The judicious choice of different photocatalyst quenchers allowed us...

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Detalles Bibliográficos
Autores principales: Georgiou, Eleni, Spinnato, Davide, Chen, Kang, Melchiorre, Paolo, Muñiz, Kilian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278488/
https://www.ncbi.nlm.nih.gov/pubmed/35919417
http://dx.doi.org/10.1039/d2sc02698h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278488/
https://www.ncbi.nlm.nih.gov/pubmed/35919417
http://dx.doi.org/10.1039/d2sc02698h

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