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Switchable photocatalysis for the chemodivergent benzylation of 4-cyanopyridines

We report a photocatalytic strategy for the chemodivergent radical benzylation of 4-cyanopyridines. The chemistry uses a single photoredox catalyst to generate benzyl radicals upon N–F bond activation of 2-alkyl N-fluorobenzamides. The judicious choice of different photocatalyst quenchers allowed us...

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Detalles Bibliográficos
Autores principales:	Georgiou, Eleni, Spinnato, Davide, Chen, Kang, Melchiorre, Paolo, Muñiz, Kilian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278488/ https://www.ncbi.nlm.nih.gov/pubmed/35919417 http://dx.doi.org/10.1039/d2sc02698h

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