Carbon dioxide reduction by an Al–O–P frustrated Lewis pair

The reaction of tBu(2)P(O)H with Bis(2)AlH (Bis = CH(SiMe(3))(2)) afforded the adduct tBu(2)P(H)–O–Al(H)Bis(2) (3). It slowly releases H(2) to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu(2)P–O–AlBis(2). It is capable of reversibly binding molecular hydrogen to afford 3, show...

Descripción completa

Detalles Bibliográficos
Autores principales: Wickemeyer, Lucas, Aders, Niklas, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, Cabrera-Trujillo, Jorge J., Fernández, Israel, Mitzel, Norbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278507/
https://www.ncbi.nlm.nih.gov/pubmed/35919415
http://dx.doi.org/10.1039/d2sc01870e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278507/
https://www.ncbi.nlm.nih.gov/pubmed/35919415
http://dx.doi.org/10.1039/d2sc01870e

Ejemplares similares