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Carbon dioxide reduction by an Al–O–P frustrated Lewis pair
The reaction of tBu(2)P(O)H with Bis(2)AlH (Bis = CH(SiMe(3))(2)) afforded the adduct tBu(2)P(H)–O–Al(H)Bis(2) (3). It slowly releases H(2) to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu(2)P–O–AlBis(2). It is capable of reversibly binding molecular hydrogen to afford 3, show...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278507/ https://www.ncbi.nlm.nih.gov/pubmed/35919415 http://dx.doi.org/10.1039/d2sc01870e |