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NHC-Ni(II)-catalyzed cyclopropene-isocyanide [5 + 1] benzannulation

Isocyanides are common compounds in fine and bulk chemical syntheses. However, the direct addition of isocyanide to simple unactivated cyclopropene via transition metal catalysis is challenging. Most of the current approaches focus on 1,1-insertion of isocyanide to M-R or nucleophilc insertion. That...

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Detalles Bibliográficos
Autores principales: Huang, Jian–Qiang, Yu, Meng, Yong, Xuefeng, Ho, Chun–Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9288548/
https://www.ncbi.nlm.nih.gov/pubmed/35842422
http://dx.doi.org/10.1038/s41467-022-31896-y