Iron salt-promoted oxidation of steroidal phenols by m-chloroperbenzoic acid: a route to possible antitumor agents

A new oxidant, containing m-chloroperoxybenzoic acid (MCPBA) and an iron salt, was developed and used for oxidation of steroidal phenols to a quinol/epoxyquinol mixture. Reaction was optimized for estrone, by varying initiators (Fe-salts), reaction temperature, time and mode of MCPBA application. A...

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Detalles Bibliográficos
Autores principales: Kop, Tatjana J., Terzić-Jovanović, Nataša, Žižak, Željko, Šolaja, Bogdan A., Milić, Dragana R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9290445/
https://www.ncbi.nlm.nih.gov/pubmed/35919136
http://dx.doi.org/10.1039/d2ra03717c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9290445/
https://www.ncbi.nlm.nih.gov/pubmed/35919136
http://dx.doi.org/10.1039/d2ra03717c

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