Cargando…

Regioselective trans‐Hydrostannation of Boron‐Capped Alkynes

Alkynyl‐B(aam) (aam=anthranilamidato) derivatives are readily available bench‐stable compounds that undergo remarkably selective reactions with Bu(3)SnH in the presence of [Cp*RuCl](4) as the catalyst. The addition follows a stereochemically unorthodox trans‐selective course; in terms of regioselect...

Descripción completa

Detalles Bibliográficos
Autores principales: Melot, Romain, Saiegh, Tomas J., Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9291331/
https://www.ncbi.nlm.nih.gov/pubmed/34240757
http://dx.doi.org/10.1002/chem.202101901