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Regioselective trans‐Hydrostannation of Boron‐Capped Alkynes
Alkynyl‐B(aam) (aam=anthranilamidato) derivatives are readily available bench‐stable compounds that undergo remarkably selective reactions with Bu(3)SnH in the presence of [Cp*RuCl](4) as the catalyst. The addition follows a stereochemically unorthodox trans‐selective course; in terms of regioselect...
Autores principales: | Melot, Romain, Saiegh, Tomas J., Fürstner, Alois |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9291331/ https://www.ncbi.nlm.nih.gov/pubmed/34240757 http://dx.doi.org/10.1002/chem.202101901 |
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