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Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF(2))(n) Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation
New dinuclear Au(I), Au(II) and Au(III) complexes containing (CF(2))(n) bridging chains were obtained. Metallomacrocycles [Au(2){μ‐(CF(2))(4)}{μ‐diphosphine}] show an uncommon figure‐eight structure, the helicity inversion barrier of which is influenced by aurophilic interactions and steric constrai...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9291513/ https://www.ncbi.nlm.nih.gov/pubmed/34490943 http://dx.doi.org/10.1002/chem.202103153 |