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Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes

A 1,8‐naphthyridine diphosphine (NDP) reacts with boron‐containing Lewis acids to generate complexes featuring a number of different naphthyridine bonding modes. When exposed to diborane B(2)Br(4), NDP underwent self‐deprotonation to afford [NDP‐B(2)Br(3)]Br, an unsymmetrical diborane comprised of f...

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Detalles Bibliográficos
Autores principales: Cui, Jingjing, Dietz, Maximilian, Härterich, Marcel, Fantuzzi, Felipe, Lu, Wei, Dewhurst, Rian D., Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292315/
https://www.ncbi.nlm.nih.gov/pubmed/34545966
http://dx.doi.org/10.1002/chem.202102721