Cargando…

Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes

A 1,8‐naphthyridine diphosphine (NDP) reacts with boron‐containing Lewis acids to generate complexes featuring a number of different naphthyridine bonding modes. When exposed to diborane B(2)Br(4), NDP underwent self‐deprotonation to afford [NDP‐B(2)Br(3)]Br, an unsymmetrical diborane comprised of f...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cui, Jingjing, Dietz, Maximilian, Härterich, Marcel, Fantuzzi, Felipe, Lu, Wei, Dewhurst, Rian D., Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292315/ https://www.ncbi.nlm.nih.gov/pubmed/34545966 http://dx.doi.org/10.1002/chem.202102721

Ejemplares similares

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry
por: Lu, Wei, et al.
Publicado: (2021)

Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes
por: Thiess, Torsten, et al.
Publicado: (2020)

Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species
por: Dhara, Debabrata, et al.
Publicado: (2022)

Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes
por: Brunecker, Carina, et al.
Publicado: (2020)

Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules
por: Dhara, Debabrata, et al.
Publicado: (2022)

{N′,N′′-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-κ(2) N′,N′′}dibromidoborane
por: Braunschweig, Holger, et al.
Publicado: (2010)

A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
por: Härterich, Marcel, et al.
Publicado: (2023)

Electron‐Rich, Lewis Acidic Diborane Meets N‐Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes
por: Widera, Anna, et al.
Publicado: (2020)

Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
por: Fantuzzi, Felipe, et al.
Publicado: (2022)

Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds
por: Brückner, Tobias, et al.
Publicado: (2022)

A Hydride‐Substituted Homoleptic Silylborate: How Similar is it to its Diborane(6)‐Dianion Isostere?
por: Gilmer, Jannik, et al.
Publicado: (2022)

Cytotoxic Phosphinoarsino and Diphosphino Pd(II) Complexes of Thiolate Amino Acids and Glutathione
por: Dhubhghaill, Orla M. Ni, et al.
Publicado: (1995)

Selective Boryl‐Anion Migration in a Vinyl sp(2)−sp(3) Diborane Induced by Soft Borane Lewis Acids
por: Fasano, Valerio, et al.
Publicado: (2018)

1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4)
por: Braunschweig, Holger, et al.
Publicado: (2010)

Adducts of the Parent Boraphosphaketene H(2)BPCO and their Decarbonylative Insertion Chemistry
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond
por: Brückner, Tobias, et al.
Publicado: (2021)

Twisting versus Delocalization in CAAC‐ and NHC‐Stabilized Boron‐Based Biradicals: The Roles of Sterics and Electronics
por: Schmid, Paul, et al.
Publicado: (2021)

Cyclo‐Dipnictadialanes
por: Nees, Samuel, et al.
Publicado: (2021)

Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound
por: Roy, Dipak Kumar, et al.
Publicado: (2020)

Exploring unsymmetrical diboranes(4) as boryl ligand precursors: platinum(ii) bis-boryl complexes
por: Drescher (née Oschmann), Wiebke, et al.
Publicado: (2019)

A Chemiluminescent Tetraaryl Diborane(4) Tetraanion
por: Budy, Hendrik, et al.
Publicado: (2021)

Chiral diboranes as catalysts for the stereoselective organopolymerization of epoxides
por: Sirin-Sariaslan, Ayla, et al.
Publicado: (2022)

Polymorphic transitions of diborane at sub- and near-megabar pressures
por: Torabi, Amin, et al.
Publicado: (2015)

Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile
por: Schön, Florian, et al.
Publicado: (2020)

An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
por: Rauch, Florian, et al.
Publicado: (2020)

Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
por: Brückner, Tobias, et al.
Publicado: (2019)

Controlled Synthesis of Oligomers Containing Main‐Chain B(sp(2))‐B(sp(2)) Bonds
por: Schorr, Fabian, et al.
Publicado: (2021)

A redox-active diborane platform performs C(sp(3))–H activation and nucleophilic substitution reactions
por: Kaese, Thomas, et al.
Publicado: (2018)

Towards the catalytic activation of inert small molecules by main-group ambiphiles
por: Dewhurst, Rian D., et al.
Publicado: (2020)

Molecular Mechanics Study of the Cyclic and Unsymmetric Diborane(4) Compounds
por: Rendtorff, N., et al.
Publicado: (2003)

Identification of diborane(4) with bridging B–H–B bonds
por: Chou, Sheng-Lung, et al.
Publicado: (2015)

Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion
por: Krebs, Johannes, et al.
Publicado: (2021)

Dicyclohexyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine–dichlorophenylborane
por: Braunschweig, Holger, et al.
Publicado: (2009)

Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes
por: Killian, Lars, et al.
Publicado: (2022)

Large-bite diboranes for the μ(1,2) complexation of hydrazine and cyanide
por: Chen, Chang-Hong, et al.
Publicado: (2018)

Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2017)

Platinum‐Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3‐Dienes and a Butatriene
por: Brunecker, Carina, et al.
Publicado: (2021)

Preparation of Polyfunctional Naphthyridines by Cobalt-Catalyzed Cross-Couplings of Halogenated Naphthyridines with Magnesium and Zinc Organometallics
por: Greiner, Robert, et al.
Publicado: (2017)

Snapshots of magnesium-centred diborane heterolysis by an outer sphere S(N)2 process
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_8605sn8fjlfih3vthvnmr21gj7