Steric Influence on Reactions of Benzyl Potassium Species with CO

Reactions of benzyl potassium species with CO are shown to proceed via transient carbene‐like intermediates that can undergo either dimerization or further CO propagation. In a sterically unhindered case, formal dimerization of the carbene is the dominant reaction pathway, as evidenced by the isolat...

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Detalles Bibliográficos
Autores principales: Wang, Tongtong, Xu, Maotong, Jupp, Andrew R., Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292647/
https://www.ncbi.nlm.nih.gov/pubmed/34592053
http://dx.doi.org/10.1002/asia.202101127

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292647/
https://www.ncbi.nlm.nih.gov/pubmed/34592053
http://dx.doi.org/10.1002/asia.202101127

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