Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity

The Brønsted acidity of the perfluorinated trialkoxysilanol {(F(3)C)(3)CO}(3)SiOH is more than 13 orders of magnitude higher than that of orthosilicic acid, Si(OH)(4), and even more for most previously known silanols. It is easily deprotonated by simple amines and pyridines to give the conjugate sil...

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Detalles Bibliográficos
Autores principales: Feige, Felix, Malaspina, Lorraine A., Rychagova, Elena, Ketkov, Sergey, Grabowsky, Simon, Hupf, Emanuel, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292728/
https://www.ncbi.nlm.nih.gov/pubmed/34550614
http://dx.doi.org/10.1002/chem.202103177

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292728/
https://www.ncbi.nlm.nih.gov/pubmed/34550614
http://dx.doi.org/10.1002/chem.202103177

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