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Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity
The Brønsted acidity of the perfluorinated trialkoxysilanol {(F(3)C)(3)CO}(3)SiOH is more than 13 orders of magnitude higher than that of orthosilicic acid, Si(OH)(4), and even more for most previously known silanols. It is easily deprotonated by simple amines and pyridines to give the conjugate sil...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292728/ https://www.ncbi.nlm.nih.gov/pubmed/34550614 http://dx.doi.org/10.1002/chem.202103177 |