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Controlled Synthesis of Oligomers Containing Main‐Chain B(sp(2))‐B(sp(2)) Bonds

A number of novel alkynyl‐functionalized diarylbis(dimethylamino)diboranes(4) are prepared by salt metathesis, and the appended alkynyl groups are subjected to hydroboration. Their reactions with monohydroboranes lead to discrete boryl‐appended diborane(4) species, while dihydroboranes induce their...

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Detalles Bibliográficos
Autores principales: Schorr, Fabian, Schopper, Nils, Riensch, Nicolas, Fantuzzi, Felipe, Neder, Marco, Dewhurst, Rian D., Thiess, Torsten, Brückner, Tobias, Hammond, Kai, Helten, Holger, Finze, Maik, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292976/
https://www.ncbi.nlm.nih.gov/pubmed/34549841
http://dx.doi.org/10.1002/chem.202103366