Sequential Hydrogen Tunneling in o‐Tolylmethylene

o‐Tolylmethylene 1 is a metastable triplet carbene that rearranges to o‐xylylene 2 even at temperatures as low as 2.7 K via [1,4] H atom tunneling. Electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) spectroscopical techniques were used to identify two conformers of 1...

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Detalles Bibliográficos
Autores principales: Lohmiller, Thomas, Sarkar, Sujan K., Tatchen, Jörg, Henkel, Stefan, Schleif, Tim, Savitsky, Anton, Sanchez‐Garcia, Elsa, Sander, Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293181/
https://www.ncbi.nlm.nih.gov/pubmed/34346532
http://dx.doi.org/10.1002/chem.202102010

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293181/
https://www.ncbi.nlm.nih.gov/pubmed/34346532
http://dx.doi.org/10.1002/chem.202102010

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