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The E(2) state of FeMoco: Hydride Formation versus Fe Reduction and a Mechanism for H(2) Evolution
The iron‐molybdenum cofactor (FeMoco) is responsible for dinitrogen reduction in Mo nitrogenase. Unlike the resting state, E(0), reduced states of FeMoco are much less well characterized. The E(2) state has been proposed to contain a hydride but direct spectroscopic evidence is still lacking. The E(...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293435/ https://www.ncbi.nlm.nih.gov/pubmed/34541722 http://dx.doi.org/10.1002/chem.202102730 |